Most of the online places sell "cured" live rock, but you have to remember that during shipping it will have some more die off and will need to be cured a little bit again. From what I understand, this should be much less time than initial curing, and less smell and all. Based on the pricing around me, for 130lbs of LR, I would get it shipped... online you can get it around $4.50/lb shipped (probably less if you were getting 100+ lbs), the cheapest I've ever seen it is $8.50/lb... that's a big difference for even 10lbs, let alone 100+.
Fish you can also get online, but remember that since the tank has to be stocked slowly, you'll have to get multiple orders, which means paying the shipping each time. Lots of more commonly available fish (most gobies, clownfish, others depending where you live) are going to be a lot cheaper to get locally, and then you can check them out to make sure they're healthy and eating. It shouldn't be tough to order online, but that shipping can get pricey.
BTW... were you planning on a quarantine tank? For a 130g, that's not a bad idea. Especially since you're planning small fish... a 10g or 20g would do fine.