The idea is to get the tank up to 5ppm once, measure the amount it took to get there...and add that every day. As soon as your nitrites hit 0...you stop adding ammonia and it should be dropping to 0 after less than 24 hours. If this is the case then you're finished!
If you're not going to add fish right away, you might test to be sure by not adding any ammonia for 24 hours and testing and then start adding that ammonia every day. As long as you add ammonia every day your tank is processing that "bioload"...so it will be ready for fish as soon as you're ready to stock it!