For a tank that large with a lot of plecos, your filtration does need a little over haul. A couple of power heads will help keep the poo suspended longer thus allowing your filters to grab it.
I would start to replace the fluvals with 405s (more GPH) and add another HOB. HOBs are hard to beat for their mechanical filtering abilities, and as much as yours are going to be picking up yo want something easy to clean.
Just to give you an idea, my 90 has the large royal, a clown plec, a small whip tail, and 3 large severums. Filtration on this tank is 2 fluval 404s with added mechanical filtration DIY in the media basket, plus 2 emperor 400s