Guessing by history I would imagine it's accumulated organics in your tank driving down your pH. The natural trend for cycled nitrogen compounds and organics is to form dissolved acidic compounds. If you have an inadequate kH alkalinity or if it's just been exhausted you'll experience what you're getting.
1. What is your kH? You need this testkit
2. What's in the tank now, including what substrate, how deep
3. How much is your skimmer producing
4 Done any water changes? You likely need to do a couple of biggies