i would not use chemicals, it is hard on fish because it causes sudden change in fish and it is best not to use chemicals when you dotn have to, crushed coral bags in your filter will harden water, shells, limestone, crushed coral added into your substrate will also harden water, you could also do what i do and add 1 tsp baking soda 1 tsp epsom salt and 1 tblspn instant ocean to your water at every water changes, this will harden the water