My PH is stuck on 7.8 no matter what time of the day I test it. On another forum, there is a guy who states that as long as cal/alk are good, you need not worry about PH, but I don't have those tests yet...
As far as gas exchange, I have a Koralia 3 agitating the surface pretty good, and the tank isn't compeltely covered. Plus, there is a skimmer injecting oxygen at least into the water it skims. I really have to get the tests soon for alk and cal.
there are buffers that are particular to saltwater and will buffer and raise alk at the same time......I suggest you test for this along with the ph and ca.