For a true blackwater biotope distilled is just fine. The biggest issue is watching your pH because the hardness is almost always very low (or will become low) with the tannins and humic acids. And if you're set on dropping the pH it might just be easier to "make" your water from "scratch" in this case.
I'm not sure what is available to you but Seachem makes some products specifically for tayloring your water.
Take a look at their website
Seachem they also have a dealer look up tool which is handy.
Specifically look at these;
1) Equilibrium: Ment to remineralize "pure" water. Perfect for helping maintain a pH, though some sort of carbonate may be needed. I think they have something for that too, don't quote me though
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2)Acid Buffer
3)Neutral Regulator
When you mix these two at a specified ratio with pure water (such as RO/DI/Distilled) it will give you a specific pH.
Their support is awesome too, I've never had to wait more than a day or two to hear back from them.
Now, all that said... do you *need* to do all this? No. And in point of fact, this *could* open a whole can-o-worms so far as pH issues.
One other thing... unless those are Sparkling Gourami's or something similar sized (like Licorise G's) into the 5.5 You'll probably have nothing but problems. Both with water quality and with aggression. It's simply too small, long term, for the ones you have.
Chris
BTW,
Sparkling G's:
Trichopsis pumila, Pygmy gourami: aquarium
Licorice G's:
Parosphromenus deissneri, Licorice gourami: aquarium There's better pic's out there. Just search the scientific name if you're interested.