I have a new 90 gallon fishless. The filter has been running for several days with the rocks and water and it has started to develop a white film on the sides of the glass that follows a horizontal pattern for some reason. I have scraped it off and it comes off grudgingly and in little clumps. The nitrites and ammonia are at zero. Ph 7.3 and nitrates 10 ppm. Also a full spectrum bulb that I keep on about 2-3 hours a day just cuz the tank looks cool even w/out fish.