Trying to drop the PH in a tank that large with a PH that high isn't going to be an easy task. Peat is pretty useless when your KH is super high. Plants also won't do squat for dropping PH. Really your best bet is to get an RO unit. You can find pretty nice ones offa Ebay. Mine makes 100 gals a day (this is always figured in 24 hrs) and the the entire kit only set me back like 70 bucks.
My guess about the neons would be your acclimation. Make it a point to ask the pet shop what their PH is. If it is around 7.0 you need to acclimate them over the course of a couple of hrs to a PH as high as yours.
Another thing to try. For a wile I was having similar issues with rummy nose tetras. No matter what I tried I just couldn't get but maybe a 3rd of the ones I would buy to live for more than a week. This was until a friend told me about what to feed new smaller tetras. Frozen baby brine shrimp ever day for 2 weeks, then gradually cutting them off until they started eating the pellet food I feed my discus. This worked very well. I did this for the next couple of batches of them and none of them have died yet. (knock on wood)
My guess about the neons would be your acclimation. Make it a point to ask the pet shop what their PH is. If it is around 7.0 you need to acclimate them over the course of a couple of hrs to a PH as high as yours.
Another thing to try. For a wile I was having similar issues with rummy nose tetras. No matter what I tried I just couldn't get but maybe a 3rd of the ones I would buy to live for more than a week. This was until a friend told me about what to feed new smaller tetras. Frozen baby brine shrimp ever day for 2 weeks, then gradually cutting them off until they started eating the pellet food I feed my discus. This worked very well. I did this for the next couple of batches of them and none of them have died yet. (knock on wood)